{"id":6845,"date":"2020-06-12T03:49:50","date_gmt":"2020-06-12T03:49:50","guid":{"rendered":"http:\/\/www.adtechamm.com\/?p=6845"},"modified":"2020-06-12T03:49:50","modified_gmt":"2020-06-12T03:49:50","slug":"aluminium-refiner","status":"publish","type":"post","link":"https:\/\/www.adtechamm.com\/tr\/aluminium-refiner\/","title":{"rendered":"Al\u00fcminyum Ar\u0131tma Tesisi"},"content":{"rendered":"

Al\u00fcminyum Ar\u0131tma Tesisi<\/strong> Al\u00fcminyum ala\u015f\u0131m\u0131 eriyiklerinin ar\u0131tma s\u00fcrecinde kullan\u0131l\u0131r. Ak\u0131\u015fkanlar\u0131n s\u0131n\u0131fland\u0131r\u0131lmas\u0131. Gereklilikler. Yayg\u0131n olarak kullan\u0131lan ak\u0131\u015fkanlar\u0131n bile\u015fimi. Uygulama alan\u0131 ve kullan\u0131m y\u00f6ntemleri.<\/p>\n

Al\u00fcminyum ve al\u00fcminyum ala\u015f\u0131mlar\u0131n\u0131n eritme s\u00fcrecinde, hidrojen ve oksitlenmi\u015f kal\u0131nt\u0131lar, al\u00fcminyum eriyi\u011fini kirleten ba\u015fl\u0131ca maddelerdir.
\nAl\u00fcminyum, oksijenle kolayca A1202 veya alt-al\u00fcmina (Al\u2082O ve A10) olu\u015fturabilir.
\nAyn\u0131 zamanda, al\u00fcminyum eriyigindeki toplam gaz\u0131n -90'\u0131n\u0131 olu\u015fturan gaz\u0131 (H) emmesi de olduk\u00e7a kolayd\u0131r; d\u00f6k\u00fcm al\u00fcminyum ala\u015f\u0131m\u0131ndaki ba\u015fl\u0131ca kusurlar olan g\u00f6zenekler ve c\u00fcruf kal\u0131nt\u0131lar\u0131, ala\u015f\u0131mda kalan gaz ve oksidasyonun neden oldu\u011fu kat\u0131 par\u00e7ac\u0131klardan kaynaklanmaktad\u0131r.
\nBu nedenle, y\u00fcksek kaliteli bir eriyik elde etmek i\u00e7in sadece do\u011fru ve uygun bir eritme i\u015flemi se\u00e7ilmekle kalmamal\u0131, ayn\u0131 zamanda eriyikin ar\u0131t\u0131lmas\u0131 ve safla\u015ft\u0131r\u0131lmas\u0131 da b\u00fcy\u00fck \u00f6nem ta\u015f\u0131maktad\u0131r.<\/p>\n

Al\u00fcminyum ve al\u00fcminyum ala\u015f\u0131m\u0131 eriyikleri i\u00e7in bir\u00e7ok ar\u0131tma ve safla\u015ft\u0131rma y\u00f6ntemi bulunmaktad\u0131r; bunlar aras\u0131nda ba\u015fl\u0131ca y\u00fczd\u00fcrme y\u00f6ntemi, ak\u0131 ar\u0131tma y\u00f6ntemi, eriyik filtreleme y\u00f6ntemi, vakum y\u00f6ntemi ve kombine y\u00f6ntem yer almaktad\u0131r.
\nBu makale, al\u00fcminyum ala\u015f\u0131m\u0131 eritme i\u015fleminde Al\u00fcminyum Rafineri cihaz\u0131n\u0131n kullan\u0131m\u0131n\u0131 ele almaktad\u0131r.<\/p>\n

Ak\u0131n\u0131n rol\u00fc<\/strong>
\nTuz ak\u0131\u015fkanl\u0131\u011f\u0131, eriyik kalitesini ve metalik al\u00fcminyum geri kazan\u0131m oran\u0131n\u0131 art\u0131rmak amac\u0131yla birincil al\u00fcminyum ve geri d\u00f6n\u00fc\u015ft\u00fcr\u00fclm\u00fc\u015f al\u00fcminyum \u00fcretiminde yayg\u0131n olarak kullan\u0131lmaktad\u0131r.
\nAk\u0131n\u0131n d\u00f6rt i\u015flevi vard\u0131r
\n1. Al\u00fcminyum eriyik ile oksit (al\u00fcmina) aras\u0131ndaki \u0131slanabilirli\u011fi de\u011fi\u015ftirmek suretiyle, al\u00fcminyum eriyik ile oksit (al\u00fcmina) aras\u0131nda kolay bir ayr\u0131\u015fma sa\u011flan\u0131r; b\u00f6ylece oksit (al\u00fcmina) b\u00fcy\u00fck \u00f6l\u00e7\u00fcde ak\u0131 maddesine kar\u0131\u015f\u0131r ve eriyikteki oksit i\u00e7eri\u011fi azal\u0131r.
\n2. Ak\u0131, eriyik y\u00fczeyindeki oksit tabakas\u0131n\u0131n durumunu de\u011fi\u015ftirebilir. Bunun nedeni, ak\u0131n\u0131n eriyik y\u00fczeyindeki g\u00fc\u00e7l\u00fc ve yo\u011fun oksit tabakas\u0131n\u0131 ince par\u00e7ac\u0131klara ay\u0131rabilmesidir; bu da eriyik i\u00e7indeki hidrojenin, oksit tabakas\u0131ndaki par\u00e7ac\u0131klar\u0131n bo\u015fluklar\u0131ndan ge\u00e7erek atmosfere ka\u00e7mas\u0131na olanak tan\u0131r.
\n3. Ak\u0131 tabakas\u0131n\u0131n varl\u0131\u011f\u0131, atmosferdeki su buhar\u0131 ile erimi\u015f al\u00fcminyum aras\u0131ndaki temas\u0131 kesebilir, hidrojenin erimi\u015f al\u00fcminyuma girmesini zorla\u015ft\u0131rabilir ve ayn\u0131 zamanda eriyik maddenin oksitlenmesini ve yanmas\u0131n\u0131 \u00f6nleyebilir.
\n4. Ak\u0131, al\u00fcminyum eriyikindeki oksitleri emerek eriyikin ar\u0131t\u0131lmas\u0131n\u0131 sa\u011flar. K\u0131sacas\u0131, ak\u0131 ar\u0131tma i\u015fleminde kal\u0131nt\u0131lar\u0131n giderilmesi, esas olarak adsorpsiyon, \u00e7\u00f6z\u00fcnme ve eriyik i\u00e7indeki oksit tabakas\u0131 ile metalik olmayan kal\u0131nt\u0131larla kimyasal etkile\u015fim yoluyla ger\u00e7ekle\u015ftirilir.<\/p>\n

\"Al\u00fcminyum<\/p>\n

Ak\u0131 s\u0131n\u0131fland\u0131rmas\u0131 ve se\u00e7imi<\/strong>
\nAr\u0131tma Ak\u0131s\u0131<\/a> s\u0131n\u0131fland\u0131rma ve gereklilikler
\nAl\u00fcminyum ala\u015f\u0131m\u0131 eritme i\u015fleminde kullan\u0131lan bir\u00e7ok farkl\u0131 t\u00fcrde ak\u0131 vard\u0131r; bunlar, kaplama maddeleri (eriyiklerin oksidatif yanmas\u0131n\u0131 \u00f6nlemek ve getterleme sa\u011flamak i\u00e7in kullan\u0131lan ak\u0131lar) ve ar\u0131tma maddeleri (gaz giderme ve kal\u0131nt\u0131lar\u0131n uzakla\u015ft\u0131r\u0131lmas\u0131 i\u00e7in kullan\u0131lan ak\u0131lar) olarak ikiye ayr\u0131labilir. Farkl\u0131 al\u00fcminyum ala\u015f\u0131mlar\u0131nda kullan\u0131lan kaplama maddesi ve ar\u0131tma maddesi birbirinden farkl\u0131d\u0131r. Ancak, al\u00fcminyum ala\u015f\u0131m\u0131 eritme i\u015fleminde kullan\u0131lan herhangi bir ak\u0131 maddesi a\u015fa\u011f\u0131daki ko\u015fullar\u0131 kar\u015f\u0131lamal\u0131d\u0131r.
\n1. Erime noktas\u0131, al\u00fcminyum ala\u015f\u0131m\u0131n\u0131n erime s\u0131cakl\u0131\u011f\u0131ndan daha d\u00fc\u015f\u00fck olmal\u0131d\u0131r.
\n2. \u00d6zg\u00fcl a\u011f\u0131rl\u0131\u011f\u0131, al\u00fcminyum ala\u015f\u0131m\u0131n\u0131nkinden daha d\u00fc\u015f\u00fck olmal\u0131d\u0131r.
\n3. Eriyikteki kal\u0131nt\u0131lar\u0131 emip \u00e7\u00f6zebilir ve eriyikten gaz\u0131 uzakla\u015ft\u0131rabilir.
\n4. Metal ve f\u0131r\u0131n astar\u0131yla kimyasal bir etkile\u015fime girmemelidir. Metal ile etkile\u015fime girerse, yaln\u0131zca metalde \u00e7\u00f6z\u00fcnmeyen inert gaz \u00fcretmeli ve ak\u0131, erimi\u015f metalde \u00e7\u00f6z\u00fcnmemelidir.
\n5. Higroskopiklik d\u00fc\u015f\u00fck olmal\u0131 ve buharla\u015fma bas\u0131nc\u0131 d\u00fc\u015f\u00fck olmal\u0131d\u0131r.
\n6. Zararl\u0131 safs\u0131zl\u0131klar ve gazlar i\u00e7ermemeli veya \u00fcretmemelidir.
\n7. Uygun viskozite ve ak\u0131\u015fkanl\u0131\u011fa sahip olmak.
\n8. \u00dcretimi kolay: fiyat\u0131 uygun.<\/p>\n

Ak\u0131 bile\u015fimi ve erimi\u015f tuzun ayr\u0131\u015ft\u0131r\u0131lmas\u0131<\/strong>
\nAl\u00fcminyum ar\u0131t\u0131c\u0131 genellikle alkali metal ve alkali toprak metal klor\u00fcrleri ile flor\u00fcrlerden olu\u015fur; ana bile\u015fenleri ise KCl, NaCl ve NaF\u2019dir. CaF\u2082, Na\u2083AlF\u2086, Na\u2082SiF\u2086 vb. Ak\u0131\u015fkan\u0131n fiziksel ve kimyasal \u00f6zellikleri (erime noktas\u0131, yo\u011funluk, viskozite, u\u00e7uculuk, higroskopiklik ve oksitlerle olan aray\u00fcz\u00fc vb.) ar\u0131tma etkisinde belirleyici bir rol oynar.<\/p>\n

Klor\u00fcr<\/strong>
\nKlor\u00fcr tuzu, al\u00fcminyum ala\u015f\u0131m\u0131 ak\u0131\u015fkan\u0131nda en yayg\u0131n temel bile\u015fendir ve 45%NaCl + 55%KCl kar\u0131\u015f\u0131m\u0131 en yayg\u0131n olarak kullan\u0131lan tuzdur.
\nKat\u0131 Al\u2082O\u2083, kal\u0131nt\u0131lar ve oksit tabakas\u0131na kar\u015f\u0131 g\u00fc\u00e7l\u00fc \u0131slatma kabiliyetleri nedeniyle (Al\u2082O\u2083 ile \u0131slatma a\u00e7\u0131s\u0131 20 dereceden fazlad\u0131r) ve NaCl ile KCl\u2019nin erime s\u0131cakl\u0131\u011f\u0131ndaki \u00f6zg\u00fcl a\u011f\u0131rl\u0131klar\u0131n\u0131n s\u0131ras\u0131yla sadece 1,55 g\/cm\u00b3 ve 1, 50 g\/cm\u00b3't\u00fcr; bu de\u011ferler al\u00fcminyum eriyiklerinin \u00f6zg\u00fcl a\u011f\u0131rl\u0131\u011f\u0131ndan \u00f6nemli \u00f6l\u00e7\u00fcde daha d\u00fc\u015f\u00fckt\u00fcr, bu nedenle al\u00fcminyum eriyik y\u00fczeyinde iyi bir \u015fekilde yay\u0131labilir, eriyik y\u00fczeyindeki oksit tabakas\u0131n\u0131 par\u00e7alayabilir ve adsorbe edebilir.
\nBununla birlikte, yaln\u0131zca klor\u00fcr tuzlar\u0131 i\u00e7eren ak\u0131\u015fta, \u00f6\u011f\u00fctme ve adsorpsiyon s\u00fcre\u00e7leri yava\u015f ilerler ve yukar\u0131daki s\u00fcreci h\u0131zland\u0131rmak i\u00e7in manuel kar\u0131\u015ft\u0131rma yap\u0131lmal\u0131d\u0131r. Klor\u00fcr, d\u00fc\u015f\u00fck y\u00fczey gerilimine ve iyi \u0131slanabilirli\u011fe sahiptir ve kaplama maddesi olarak uygundur. Bunlar aras\u0131nda, CCl\u2084, SiCl\u2084, AlCl\u2083 gibi molek\u00fcler kristal yap\u0131ya sahip klor\u00fcr tuzlar\u0131 tek ba\u015f\u0131na safla\u015ft\u0131r\u0131c\u0131 olarak kullan\u0131labilirken, LiCl, NaCl, KCl, MgCl\u2082 gibi iyonik kristal yap\u0131ya sahip klor\u00fcr tuzlar\u0131 kar\u0131\u015f\u0131k tuz ak\u0131\u015f\u0131na uygundur.<\/p>\n

Flor\u00fcr<\/strong>
\nKlor\u00fcr tuzu kar\u0131\u015f\u0131m\u0131na NaF ekleyin. Na\u2083AlF\u2086, CaF\u2082. Az miktarda flor tuzu, esas olarak Al\u2082O\u2083\u2019\u00fcn adsorpsiyonu ve \u00e7\u00f6z\u00fcnmesi gibi ar\u0131tma i\u015flevi g\u00f6r\u00fcr.
\nFlor\u00fcr tuzu, eriyik y\u00fczeyindeki oksit tabakas\u0131n\u0131 da etkili bir \u015fekilde giderebilir ve gaz giderme etkisini art\u0131rabilir.
\nBunun nedeni \u015fudur:
\na) Flor\u00fcr, erimi\u015f al\u00fcminyumla kimyasal olarak reaksiyona girerek gaz halindeki AlF, SiF\u2084, BF\u2083 vb. bile\u015fikleri olu\u015fturabilir. Bunlar, oksit tabakas\u0131n\u0131n erimi\u015f al\u00fcminyumdan ayr\u0131lmas\u0131n\u0131 mekanik olarak kolayla\u015ft\u0131r\u0131r; ayr\u0131ca oksit tabakas\u0131n\u0131 s\u0131k\u0131\u015ft\u0131rarak ak\u0131 i\u00e7ine iter.
\nb) Yukar\u0131daki reaksiyonun ger\u00e7ekle\u015fti\u011fi aray\u00fczde olu\u015fan ak\u0131m, oksit tabakas\u0131n\u0131n \u201cy\u0131kanmas\u0131na\u201d ve par\u00e7alanmas\u0131na da neden olur. Bu nedenle, flor tuzunun varl\u0131\u011f\u0131, al\u00fcminyum eriyik y\u00fczeyindeki oksit tabakas\u0131n\u0131n bozulma s\u00fcrecini \u00f6nemli \u00f6l\u00e7\u00fcde h\u0131zland\u0131r\u0131r ve eriyik i\u00e7indeki hidrojen daha kolay bir \u015fekilde d\u0131\u015far\u0131 \u00e7\u0131kabilir.
\nc) Flor\u00fcr (\u00f6zellikle CaF\u2082), kar\u0131\u015f\u0131k erimi\u015f tuzun y\u00fczey gerilimini art\u0131rabilir, adsorbe edilen oksidin erimi\u015f tuzunu k\u00fcresel hale getirebilir, eriyikten ayr\u0131lmas\u0131n\u0131 kolayla\u015ft\u0131rabilir ve al\u00fcminyumla sar\u0131lm\u0131\u015f kat\u0131 erimi\u015f c\u00fcrufun neden oldu\u011fu kayb\u0131 azaltabilir, ayr\u0131ca ak\u0131\u015fkan\u0131n y\u00fczey geriliminin artmas\u0131 nedeniyle, eriyik ak\u0131\u015fkan\u0131n adsorpsiyon ve kaps\u00fclleme s\u00fcrecini h\u0131zland\u0131r\u0131r.<\/p>","protected":false},"excerpt":{"rendered":"

Aluminium Refiner is used in the purification process of aluminum alloy melts. Classification of fluxes. Requirements. Composition of commonly used fluxes. Scope of application and methods of use. In the smelting process of aluminum and aluminum alloys, hydrogen and oxidized inclusions are the main substances…<\/p>","protected":false},"author":1,"featured_media":6846,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[1],"tags":[],"yoast_head":"\nAluminium Refiner is used in the purification process of aluminum alloy<\/title>\n<meta name=\"description\" content=\"Aluminium Refiner is used in the purification process of aluminum alloy melts. Classification of fluxes. 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